I love Pushing Daisies, apart from all the amazing dresses, pretty hair and super lush eyelashes, Charlotte Charles (aka Chuck) always had something supernatural about her. In the series she's supposed to be dead, so I really liked the idea of her being someone you could totally dress up for in honour of Halloween. I'd love to throw on a pretty dress, tousle my hair, put on a flick of eyeliner & lashings of mascara, bake apple pies & make my own honey.
P.S. If you're a couple and you're being super cute you could go as Chuck & Ned <3